Tiff was originally created by a company called Aldus, and is now owned by Adobe systems, it is a file format for storing images, including line art and photographs. It was created due to the popularity of scanners and was thought-up to become the standard scanned image file format. It is a popular format for high-colour-depth images and it has also been adapted to accommodate greyscale images.
A TIFF file is made up of many different blocks which define the palette data or the LZW-compressed body among other things. The byte order is either Motorola or Intel depending on the first word. if it is MM, then you have Motorola byte ordering and likewise if it is II it means you have Intel byte ordering. Each TIFF file begins with an image file header which then points to an image file directory which contains the image data and image information.
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PDF is a file format developed by Adobe Systems for representing documents in a manner that is separate from the original operating system, application or hardware from where it was originally created. A PDF file can be any length, contain any number of fonts and images and is designed to enable the creation and transfer of printer-ready output.
Each PDF file encapsulates a complete description of a 2D document (and, with the advent of Acrobat 3D, embedded 3D documents) that includes the text, fonts, images and 2D vector graphics that compose the document. They do not encode information that is specific to the application software, hardware, or operating system used to create or view the document.